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| Synthesis of Novel Allylic Ether Compounds Catalysed by FeCl3 |
| XU Xing-zhu, GU Zhan-shou, LI Zheng-yi, SUN Xiao-qiang, WANG Zhi-ming |
| School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China |
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Abstract Nine allylic ether compounds(2a~2i; 2c, 2e~2i were novel compounds) were synthesized by intermolecular nucleophilic substitution reaction, using allylic alcohols(1a~1i) and ethanol as starting materials, FeCl3 as catalyst. The yields of 2a~2i were 80%~95%. The structures were characterized by 1H NMR, 13C NMR and HR-ESI-MS. Effects of catalyst, solvent, reaction temperature and time on yield of 2a were investigated. The results showed that the yield of 2a was 95% under the optimized reaction conditions［1a 0.5 mmol, FeCl3 4 mg, EtOH 2.5 mmol, CH2Cl2 as solvent， reacted at rt for 0.8 h］.
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Received: 17 March 2015
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2016, Vol. 24 
